Oxalate is the oxalate ion, a dianion having the chemical formula
It is derived from oxalic acid and is commonly found in various salts known as oxalates.
Molecular Weight: The molecular weight of the oxalate ion is roughly 88.02 g/mol.
Structure: Oxalate ions have a planar structure with a central C-C bond, where each carbon is bound to two oxygen atoms, usually bidentate.
Solubility: Many oxalate salts are but weakly soluble in water. Solubility of the salt can vary considerably with the identity of the metal cation.
Appearance: Oxalate salts may be colourless crystals or white powders.
Melting Point: The melting points of oxalate salts vary; for instance, the calcium oxalate monohydrate has a melting point near about 200 °C.
Acidity: Oxalic acid is a weak acid; the oxalate ion can be also used as a ligand, forming complexes with metal ions.
Biological Role: Oxalates are found in many plants and can form complexes that precipitate in the presence of calcium that can cause stones in human kidneys.
1. Weak Acid: Oxalic acid is a diprotic acid, thus it can dissolve in two steps through the breaking for oxalate ions:
The oxalate ion can act as a weak base by accepting protons to give the oxalic acid.
2. Complex Formation
Chelating Agent: Oxalate can act as a bidentate ligand, producing stable complexes with a variety of metal ions, such as: Ca2+, Mg2+, and iron. This characteristic is exploited both in biological and analytical chemistry.
3. Redox Reactions
Redox Behavior: In strong oxidizing conditions, oxalate gets oxidized to carbon dioxide and formic acid or other products. This behavior finds some relevance in organic synthesis and some analytical techniques.
4. Reactions with Metal Salts
Precipitation: Oxalate ions react with calcium and barium, etc., to give insoluble oxalate salts, such as calcium oxalate. This property is used for the determination of calcium and other metals.
5. Thermal Decomposition
Thermal Decomposition: Oxalate salts decompose on heating, giving carbon dioxide and carbon monoxide. Oxidation by Strenuous Oxidants Oxidation reactions:
Oxalate can be oxidized by a strong oxidant like potassium permanganate or hydrogen peroxide, usually in the presence of acid.
6. Esterification
Esterification Reaction: Oxalic acid reacts with an alcohol to give oxalate ester and finds several applications in the synthesis of various compounds.
Agriculture:
Oxalates occur in all plants, and can bind calcium ions. Recognition of its function assists in the management of nutrient pools in the soil as well as in the health of the plants.
Food Technology:
It is found in a vast number of foodstuffs (e.g. spinach, rhubarb). As a nutrient component, the interaction with calcium has relevance to dietary advice.
Medicine:
High levels of oxalate are toxic and cause kidney stones. The interest in medicine is in dietary management of oxalate to prevent stone formation.
Analytical Chemistry:
Oxalate is used as a chelating agent for the complexometric titration of metal ions in several samples.
Organic Synthesis:
Oxalate is used as a precursor for preparing other organic compounds, like esters and oxalic acid derivatives.
Industrial Applications:
Oxalate is used as a dye and bleach preparative. The properties are also used in the textile and paper industries.
Environmental Chemistry:
The knowledge about the formation and degradation of oxalate is very important to understand the decompositions of organic matter in carbon cycling.
Oxalate, in its ionic form, is a chemical agent serving multifunctional purposes in various fields. Its chemistry enables it to be a weak acid, chelating agent, and a redox participant. Its properties make it useful in agriculture, nutrition, medicine, analytical chemistry, and industrial applications.
Such a mechanism would require knowing the behavior and implications of oxalate in biological systems, food, and the environment in order to apply it optimally and identify any possible health risks. It is through continued research that one can utilize the properties of oxalate while trying to address challenges associated with its presence in foods and the physiological effects.
Other Related Sections
NCERT Solutions | Sample Papers | CBSE SYLLABUS| Calculators | Converters | Stories For Kids | Poems for Kids| Learning Concepts | Practice Worksheets | Formulas | Blogs | Parent Resource
Admissions Open for
Oxalate is the oxalate ion, a dianion having the chemical formula
It is derived from oxalic acid and is commonly found in various salts known as oxalates.
Molecular Weight: The molecular weight of the oxalate ion is roughly 88.02 g/mol.
Structure: Oxalate ions have a planar structure with a central C-C bond, where each carbon is bound to two oxygen atoms, usually bidentate.
Solubility: Many oxalate salts are but weakly soluble in water. Solubility of the salt can vary considerably with the identity of the metal cation.
Appearance: Oxalate salts may be colourless crystals or white powders.
Melting Point: The melting points of oxalate salts vary; for instance, the calcium oxalate monohydrate has a melting point near about 200 °C.
Acidity: Oxalic acid is a weak acid; the oxalate ion can be also used as a ligand, forming complexes with metal ions.
Biological Role: Oxalates are found in many plants and can form complexes that precipitate in the presence of calcium that can cause stones in human kidneys.
1. Weak Acid: Oxalic acid is a diprotic acid, thus it can dissolve in two steps through the breaking for oxalate ions:
The oxalate ion can act as a weak base by accepting protons to give the oxalic acid.
2. Complex Formation
Chelating Agent: Oxalate can act as a bidentate ligand, producing stable complexes with a variety of metal ions, such as: Ca2+, Mg2+, and iron. This characteristic is exploited both in biological and analytical chemistry.
3. Redox Reactions
Redox Behavior: In strong oxidizing conditions, oxalate gets oxidized to carbon dioxide and formic acid or other products. This behavior finds some relevance in organic synthesis and some analytical techniques.
4. Reactions with Metal Salts
Precipitation: Oxalate ions react with calcium and barium, etc., to give insoluble oxalate salts, such as calcium oxalate. This property is used for the determination of calcium and other metals.
5. Thermal Decomposition
Thermal Decomposition: Oxalate salts decompose on heating, giving carbon dioxide and carbon monoxide. Oxidation by Strenuous Oxidants Oxidation reactions:
Oxalate can be oxidized by a strong oxidant like potassium permanganate or hydrogen peroxide, usually in the presence of acid.
6. Esterification
Esterification Reaction: Oxalic acid reacts with an alcohol to give oxalate ester and finds several applications in the synthesis of various compounds.
Agriculture:
Oxalates occur in all plants, and can bind calcium ions. Recognition of its function assists in the management of nutrient pools in the soil as well as in the health of the plants.
Food Technology:
It is found in a vast number of foodstuffs (e.g. spinach, rhubarb). As a nutrient component, the interaction with calcium has relevance to dietary advice.
Medicine:
High levels of oxalate are toxic and cause kidney stones. The interest in medicine is in dietary management of oxalate to prevent stone formation.
Analytical Chemistry:
Oxalate is used as a chelating agent for the complexometric titration of metal ions in several samples.
Organic Synthesis:
Oxalate is used as a precursor for preparing other organic compounds, like esters and oxalic acid derivatives.
Industrial Applications:
Oxalate is used as a dye and bleach preparative. The properties are also used in the textile and paper industries.
Environmental Chemistry:
The knowledge about the formation and degradation of oxalate is very important to understand the decompositions of organic matter in carbon cycling.
Oxalate, in its ionic form, is a chemical agent serving multifunctional purposes in various fields. Its chemistry enables it to be a weak acid, chelating agent, and a redox participant. Its properties make it useful in agriculture, nutrition, medicine, analytical chemistry, and industrial applications.
Such a mechanism would require knowing the behavior and implications of oxalate in biological systems, food, and the environment in order to apply it optimally and identify any possible health risks. It is through continued research that one can utilize the properties of oxalate while trying to address challenges associated with its presence in foods and the physiological effects.
Other Related Sections
NCERT Solutions | Sample Papers | CBSE SYLLABUS| Calculators | Converters | Stories For Kids | Poems for Kids| Learning Concepts | Practice Worksheets | Formulas | Blogs | Parent Resource
Admissions Open for
The chemical formula for Aluminum Bromide is AlBr₃.
Aluminum Bromide is used primarily as a catalyst in organic synthesis, particularly in the bromination of aromatic compounds. It also has applications in the production of other chemicals and in certain types of chemical research.
CBSE Schools In Popular Cities